Method Statement BOD

@(#) Uncontrolled Document bod.html Version 1.1 Last Revised on 12/09/02




Contents

Introduction

Principle

Performance Characteristics

Range of Application

Limit of Detection

Analytical Quality Control

References

Introduction

The performance of this method is validated in accordance with internationally recognised procedures.

This procedure describes the determination of biological oxygen demand (BOD) in waters by incubation and determination of dissolved oxygen by means of a dissolved oxygen meter.

Principle

BOD (5 day) is determined by dilution of an aliquot of air-saturated sample and, if appropriate, "seeding" with a suitable source of micro-organisms. The container is then incubated for five days at 20 degrees Centigrade in the dark. The amount of oxygen absorbed is determined by means of a dissolved oxygen meter.

Performance Characteristics

Substances Determined

Uptake of dissolved oxygen by the sample during 5 days at 20 degrees centigrade in the dark.

Range of Application

  • Aqueous samples up to 6.0 mg / l without dilution.

Limit of Detection

  • Aqueous samples 0.1 mg / l

Analytical Quality Control

Analytical quality control is maintained by a number of measures:

  • Multi-point calibration with authentic standards (with defined minimum performance characteristics)

  • Analysis of control samples within each analytical batch, such as independent standards, matrix spikes or reference materials.

  • Participation in external proficiency testing and interlaboratory schemes such as LGC CONTEST, HSE WASP, CSL FAPAS

References

5 Day Biochemical Oxygen Demand (BOD5) in Waters, DOE Methods for the Examination of Waters and Associated Materials, published by HMSO. 1988.


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